Originally posted by sigfreund:
By “shot” shells I thought you were referring to cartridges loaded with birdshot, so I’m glad I looked in.

I wouldn’t usually call black marks on a fired cartridge “powder burns” but rather firing residues of the same sort that end up in the barrel and on other parts of the gun. The presence of fired powder residues on cartridge cases is hardly unusual; it’s common in fact. If the residues are unusually heavy, though, it may indicate that the case didn’t expand as quickly or as fully as other cases might, thereby allowing powder gas to flow back between the case and the chamber wall. That can have a couple of likely causes. One is that the case itself is resistant to expanding and sealing the chamber because the metal is thicker or stronger than usual. The other, and probably more common reason is that the load is low powered.
I doubt I would be worried about the phenomenon, but if you can post photos of the cases for us to look at, we would have a better idea if the residues are unusually heavy.
As a side note, the HK P7 pistol has flutes in the chamber that are specifically intended to permit gas to flow between the chamber wall and the cartridge case to enhance extraction.
Welcome to the forum.